Cation disordering in heat-treated anthophyllites through oxidation and dehydrogenation     

K. Ishida 《Physics and Chemistry of Minerals》1998,25(2):160-167

Oxidation and dehydrogenation processes for heat-treated anthophyllites were investigated using Mössbauer and infrared spectroscopy. At temperatures from 350°C to about 650°C, Fe²⁺ at the M1 and M3 sites oxidizes, yielding Fe³⁺ + one electron. A proton from the (OH)^– is liberated and combines with this electron to form a hydrogen atom; and some Fe²⁺ ions at the M2 and M4 sites exchange with Mg at the M1 and M3 sites and then are oxidized in a similar way; at higher temperature, OH remaining in the (MgMgMg/Fe³⁺)-(OH)-configuration are dehydrogenated by decomposition of the amphibole to orthopyroxene and quartz. During oxidation and dehydrogenation of anthophyllite, there is disordering of Mg and Fe at the M1, M2, M3 and M4 sites in all samples studied. When all Fe²⁺ is oxidized, the site occupancies of at the M4 and M1, M2, M3 sites become identical, indicating that Mg and Fe³⁺ are completely disordered at these sites.  相似文献   

Interaction Between Wind and Snow Surface     

Shun’ichi Kobayashi  Tamotu Ishida 《Boundary-Layer Meteorology》1979,16(3):35-47

The horizontal and vertical wind velocity fluctuations were measured using two sonic anemometers at a height of 135 cm above a snow surface under a transverse snow wave-forming condition. A snow-wave was formed when the wind at a height of 1 m blew at a speed of more than 7 m s⁻¹ after an approximate accumulation of from 10 to 20 cm of new snow on a snowfield. For example, when a snow-wave had a wavelength of 10 m and a wave height of 15 to 20 cm, the measured horizontal and vertical velocity components showed that they had a frequency peak of 0.7 Hz in coherence and co-spectrum corresponding to this wavelength. The results suggest that wind turbulence and snow-wave formation interact with each other.  相似文献   

Interaction between wind and snow surface     

Shun'ichi Kobayashi  Tamotu Ishida 《Boundary-Layer Meteorology》1979,16(1):35-47

The horizontal and vertical wind velocity fluctuations were measured using two sonic anemometers at a height of 135 cm above a snow surface under a transverse snow wave-forming condition. A snow-wave was formed when the wind at a height of 1 m blew at a speed of more than 7 m s^–1 after an approximate accumulation of from 10 to 20 cm of new snow on a snowfield. For example, when a snow-wave had a wavelength of 10 m and a wave height of 15 to 20 cm, the measured horizontal and vertical velocity components showed that they had a frequency peak of 0.7 Hz in coherence and co-spectrum corresponding to this wavelength. The results suggest that wind turbulence and snow-wave formation interact with each other.  相似文献   

Sedimentary records of reduction in resting egg production of <Emphasis Type="Italic">Daphnia galeata</Emphasis> in Lake Biwa during the 20th century: a possible effect of winter warming     

Narumi K. Tsugeki  Seiji Ishida  Jotaro Urabe 《Journal of Paleolimnology》2009,42(2):155-165

To clarify long-term variations in the resting egg production of Daphnia galeata in Lake Biwa during the 20th century, we examined an abundance of plankton remains and ephippia in a 26-cm sediment core with a time resolution of approximately 2–6 years. Historical changes shown by these plankton remains indicated that the Daphnia population has not produced resting eggs since the 1980s, but it has remained the most abundant zooplankton species in the lake. Plankton monitoring data collected from 1966 to 2000 revealed that the overwintering individuals (January–March) of D. galeata plankters showed a significant increasing trend in recent years, such increase being negatively correlated with ephippial abundance in the sediment samples. Further analyses showed that the dominant phytoplankton in winter has changed from large inedible diatoms to edible flagellated algae, probably due to changes in vertical mixing regimes resulting from winter warming. These changes that occurred in the last several decades suggest that global warming has improved winter food conditions and thus enabled the Daphnia plankton to maintain its population without producing resting eggs in Lake Biwa.  相似文献   

Changes of microbial populations in a ship's ballast water and sediments on a voyage from Japan to Qatar     

Mimura H  Katakura R  Ishida H 《Marine pollution bulletin》2005,50(7):751-757

Colony-forming eutrophic marine microorganisms in ballast water were counted in samples taken on board in 2002 and 2003. In the ballast water in Japan, viable cell numbers were highly variable but not by more than 10(5.1) colony-forming units (CFU)ml(-1) regardless of season. Even when ballast water was discharged offshore, values varied but not by more than 10(5.0) CFUml(-1). The effectiveness of the ballast water exchange was unconfirmed, except for the February 2003 voyage. No microbial colonies were counted in the reloaded ballast water in the high seas on that voyage, which contributed to the reduction of the total number of viable cells sampled in the discharged ballast water at the Ras Laffan port in Qatar. In sediment samples, the values of 10(5.2) - 10(6.0) CFUml(-1) were estimated for all seasons in which voyages took place. The maximum of the marine Vibrio species, 110 CFUml(-1), was observed in the ballast water sample taken in July 2003. The estimated total viable cell numbers in sediments were higher than those counted in the ballast water throughout the experiments, indicating the importance of sediment management as well as ballast water management on vessels traveling from Japan.  相似文献   

Distribution of Fe among octahedral sites and its effect on the crystal structure of pumpellyite     

Mariko Nagashima  Takahiro Ishida  Masahide Akasaka 《Physics and Chemistry of Minerals》2006,33(3):178-191

Two pumpellyites with the general formula W ₈ X ₄ Y ₈ Z ₁₂O_56-n (OH) _n were studied using ⁵⁷Fe Mössbauer spectroscopic and X-ray Rietveld methods to investigate the relationship between the crystal chemical behavior of iron and structural change. The samples are ferrian pumpellyite-(Al) collected from Mitsu and Kouragahana, Shimane Peninsula, Japan. Rietveld refinements gave Fe(X):Fe(Y) ratios (%) of 41.5(4):58.5(4) for the Mitsu pumpellyite and 46(1):54(1) for the Kouragahana pumpellyite, where Fe(X) and Fe(Y) represent Fe content at the X and Y sites, respectively. The Mössbauer spectra consisted of two Fe²⁺ and two Fe³⁺ doublets for the Mitsu pumpellyite, and one Fe²⁺ and two Fe³⁺ doublets for the Kouragahana pumpellyite. In terms of the area ratios of the Mössbauer doublets and the Fe(X):Fe(Y) ratios determined by the Rietveld refinements, Fe²⁺(X):Fe³⁺(X):Fe³⁺(Y) ratios are determined to be 22:14:64 for the Mitsu pumpellyite and 27:8:65 for the Kouragahana pumpellyite. By applying the Fe²⁺:Fe³⁺-ratio determined by the Mössbauer analysis and the site occupancies of Fe at the X and Y sites given by the Rietveld method together with chemical analysis, the resulting formula of the Mitsu and Kouragahana pumpellyites are established as Ca₈(Fe _0.88 ²⁺ Mg_0.68Fe _0.77 ³⁺ Al_1.66)_Σ3.99(Al_5.67Fe _2.34 ³⁺ )_Σ8.01Si₁₂O_42.41(OH)_13.59 and Ca₈(Mg_1.24Fe _0.65 ²⁺ Fe _0.46 ³⁺ Al_1.66)_Σ4.01(Al_6.71Fe _1.29 ³⁺ )_Σ8.00Si₁₂O_42.14(OH)_13.86, respectively. Mean Y–O distances and volumes of the YO₆ octahedra increase with increasing mean ionic radii, i.e., the Fe³⁺→Al substitution at the Y site. However, change of the sizes of XO₆ octahedra against the mean ionic radii at the X site is not distinct, and tends to depend on the volume change of the YO₆ octahedra. Thus, the geometrical change of the YO₆ octahedra with Fe³⁺→Al substitution at the Y site is essential for the structural changes of pumpellyite. The expansion of the YO₆ octahedra by the ionic substitution of Fe³⁺ for Al causes gradual change of the octahedra to more symmetrical and regular forms.  相似文献   

Rare Earth Elements in Hydrothermally Altered Granitic Rocks in the Ranong and Takua Pa Tin‐Field,Southern Thailand     

Akira Imai  Kotaro Yonezu  Kenzo Sanematsu  Takashi Ikuno  Shingo Ishida  Koichiro Watanabe  Visut Pisutha‐Arnond  Somchai Nakapadungrat  Jarupong Boosayasak 《Resource Geology》2013,63(1):84-98

Geochemical studies were conducted on the hydrothermally altered granitic rocks in the Ranong and Takua Pa tin‐fields in southern Thailand in order to investigate the mode of occurrence of REE (rare earth elements), with emphasis placed on a potential REE resource associated with granitic rocks in the Southeast Asian Tin Belt. The total REE (ΣREE) content of altered granitic rocks ranges from 130 to 350 ppm at Haad Son Paen (which is presently mined for kaolin clay) in the Ranong tin‐field, and that of altered granitic rocks and kaolinite veinlets reaches up to 424 ppm and 872 ppm, respectively, at Nok Hook in the Takua Pa tin‐field. Rare earth elements in the altered granitic rocks and kaolinite veinlets show a relatively flat chondrite‐normalized pattern, thus enriched in heavy REE compared with the original granitic rocks and their weathered crusts. At Nok Hook (Takua Pa), the ΣREE content of kaolinite separated from an altered granitic rock by elutriation is 1313 ppm, a ΣREE amount about four times higher than that of whole‐rock composition of the altered granitic rock. Chondrite‐normalized REE patterns of the elutriated kaolinite and of the altered granite are relatively flat. Sequential extraction experiments suggest that 41 and 85 percent of REE are present as ion exchangeable‐form in the altered granitic rock, and in the kaolinite veinlets, respectively. In addition, more than 90% of REE in the kaolinite veinlets are present as the acid‐soluble state. On the other hand, the ΣREE content of kaolinite veinlets and of the kaolinite concentrated by elutriation from an altered granitic rock at Haad Som Paen (Ranong) is 70 ppm and 75 ppm, respectively, thus enrichment of REE in kaolinite was not confirmed. In addition, by the sequential extraction experiments, 23% and 4% of REE were extracted from the altered granitic rock and the kaolinite veinlets at Haad Som Paen. In the altered granitic rocks at Haad Som Paen, REE are present as refractory phases, and REE in the acid‐soluble states had been leached by hydrothermal fluid.  相似文献   

Effectiveness of superelastic bars for seismic rehabilitation of clay‐unit masonry walls     

Kshitij C. Shrestha  Yoshikazu Araki  Takuya Nagae  Toshihiro Omori  Yuji Sutou  Ryosuke Kainuma  Kiyohito Ishida 《地震工程与结构动力学》2013,42(5):725-741

This paper presents the results on shaking table tests of half‐scale brick walls performed to investigate the effectiveness of newly developed Cu–Al–Mn superelastic alloy (SEA) bars in retrofitting of historical masonry constructions. Problems associated with conventional steel reinforcing bars lie in degradation of stiffness and strength, or pinching phenomena, under cyclic loading, and presence of large residual cracks in structures during and after intense earthquakes. This paper attempts to resolve the problems by applying newly developed Cu–Al–Mn SEA bars, characterized by large recovery strain, low material cost, and high machinability, as partial replacements for steel bars. Sets of unreinforced, steel reinforced, and SEA‐reinforced specimens are subjected to scaled earthquake excitations in out‐of‐plane direction. Whereas steel‐reinforced specimens showed large residual inclinations, SEA‐reinforced specimens resulted in stable rocking response with slight residual inclinations. Corresponding nonlinear finite element (FE) models are developed to simulate the experimental observations. The FE models are further used to examine the sensitivity of the response with respect to the variations in experimental conditions. Both the experimental and numerical results demonstrate the superiority of Cu–Al–Mn SEA bars to conventional steel reinforcing bars in avoiding pinching phenomena. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Rediscovering wood-laden debris flow studies: A perspective from Japan     

Kenta Koyanagi  Taku Yamada  Koji Ishida 《地球表面变化过程与地形》2023,48(1):104-118

Debris flow is one of the dominant processes distributing large wood (LW) within mountainous catchments. However, little has been reviewed on wood-laden debris flow (WLDF), presumably owing to limited reviewable works. This article, therefore, navigates the international readers through 40 years of WLDF studies, most of which have been published only in Japanese. Firstly, we reviewed the historical development of Japanese WLDF particularly focusing on the 1980s and the 1990s. A series of post-disaster fieldworks from the July 1982 Nagasaki flood to the July 1990 Kumamoto flood provided 32 catchment-scale wood budgeting data; empirical relationships among drainage area, dominant tree species, sediment yield, and wood loads associated with single debris flow disasters were illustrated. Secondly, the characteristics of WLDF were summarized based on relevant previous studies on the recruitment, transport, and deposition processes of LW during debris flows. Thirdly, we discussed the connectivity between those Japanese WLDF studies and international LW studies by relating/contrasting their research approaches and spatiotemporal scales. In contrast to global LW research trends, Japanese WLDF studies have almost exclusively regarded LW as hazardous materials (i.e., “driftwood” or “woody debris”) that need to be retained upstream of the inhabited areas. Those practice-oriented WLDF studies were concentrated on drainage areas of 10⁻² to 10⁰ km², representing 1–6 orders of magnitude smaller spatial scales than those generally covered by existing international LW studies. Strongly motivated by engineering requirements, “dynamic” interactions between debris flows and LW during floods have also been physically presented, mainly based on unique laboratory experiments involving steep flume (> 0.05) and mobile bed conditions. Finally, some future works for WLDF were briefly stated from practical and scientific perspectives. By “rediscovering” those WLDF studies domestically developed in Japanese debris flow channels since the 1980s, a more comprehensive understanding of LW dynamics in the river system may be achieved.  相似文献